Aquabis(1H-imidazole-kappa N-3)bis(4-methylbenzoato-kappa O-2,O ')cadmium(II)

作者：Song, Wen-Dong^*; Ji, Li-Li; Huang, Xiang-Hu

来源：Acta Crystallographica Section E-Structure Reports Online, 2008, 64: M714-U888.

DOI：10.1107/S1600536808011331

In the title compound, [Cd(C8H7O2)(2)(C3H4N2)(2)(H2O)], the Cd-II atom is coordinated by four carboxylate O atoms from two bidentate chelating 4-methylbenzoate ligands, two N atoms from two imidazole ligands and one water molecule in a distorted pentagonal bipyramidal geometry. Intermolecular O-H center dot center dot center dot O hydrogen bonds between the coordinated water molecule and the carboxylate O atoms of 4-methylbenzoate lead to an infinite chain. These chains are further self-assembled into a two-dimensional layer through O-H center dot center dot center dot O hydrogen bonds between the imidazole ligands and carboxylate groups. One of the imidazole ligands is disordered over two positions with site-occupancy factors of 0.737 (4) and 0.263 (4).

• 出版日期2008-5
• 单位广东海洋大学