Dinuclear chiral vanadium catalysts for oxidative coupling of 2-naphthols via a dual activation mechanism

作者：Takizawa Shinobu; Katayama Tomomi; Sasai Hiroaki^*

来源：Chemical communications, 2008, (35): 4113-4122.

DOI：10.1039/b806016a

This review describes our recent efforts in the development of chiral dinuclear vanadium complexes that work as dual activation catalysts for the oxidative coupling of 2-naphthols. The dinuclear vanadium(IV) complex (R(a),S,S)-1a was prepared by complexation of VOSO(4) with the Schiff base derived from (R)-3,3'-diformyl-2,2'-dihydroxy-1,1'-binaphthyl (15) and (S)-tert-leucine. Since the dinuclear vanadium(IV) complex was found to be readily oxidized to afford a corresponding vanadium( V) species during preparation in air, a new synthetic procedure using VOCl(3) has been applied towards dinuclear vanadium(V) complexes (R(a),S,S)-2 and (R(a),S,S)-3. To the best of our knowledge, (R(a),S,S)-1a, 2 and 3 show considerably higher catalytic activity than previously reported vanadium complexes for the oxidative coupling of 2-naphthols.

• 出版日期2008