Mild, Safe, and Versatile Reagents for (CF2)(n) Transfer and the Construction of Fluoroalkyl-Containing Rings

作者：Kaplan Peter T; Xu Long; Chen Bo; McGarry Katherine R; Yu Siqi; Wang Huan; Vicic David A^*

来源：Organometallics, 2013, 32(24): 7552-7558.

DOI：10.1021/om401016k

The preparation of new dizinc reagents [(MeCN)(2)Zn((CF2)(n))(2)Zn(MeCN)(2)] (n = 3, 4, and 6) is reported. We show that the C4 reagent can readily transmetalate nickel to form a mononuclear perfluoronickela-cycle. We also demonstrate that the reagents can be used to prepare novel fluoroorganics containing either perfluoroalkyl ring systems or perfluoroalkyl linked arenes under relatively mild conditions.

• 出版日期2013-12-23