An Innovative Metal Ions Sensitive %26quot;Test Paper%26quot; Based on Virgin Nanoporous Silicon Wafer: Highly Selective to Copper(II)

作者：Li Shaoyuan; Chen Xiuhua; Ma Wenhui; Ding Zhao; Zhang Cong; Chen Zhengjie; He Xiao; Shang Yudong; Zou Yuxin

来源：Scientific Reports, 2016, 6(1): 36654.

DOI：10.1038/srep36654

Developing an innovative "Test Paper" based on virgin nanoporous silicon (NPSi) which shows intense visible emission and excellent fluorescence stability. The visual fluorescence quenching "Test Paper" was highly selective and sensitive recognizing Cu2+ at mu mol/L level. Within the concentration range of 5 x 10(-7) -50 x 10(-7) mol/L, the linear regression equation of I-PL = 1226.3-13.6[C-Cu (2+)] (R = 0.99) was established for Cu2+ quantitative detection. And finally, Cu2+ fluorescence quenching mechanism of NPSi prober was proposed by studying the surface chemistry change of NPSi and metal ions immersed-NPSi using XPS characterization. The results indicate that SiHx species obviously contribute to the PL emission of NPSi, and the introduce of oxidization state and the nonradiative recombination center are responsible for the PL quenching. These results demonstrate how virgin NPSi wafer can serve as Cu2+ sensor. This work is of great significant to promote the development of simple instruments that could realize rapid, visible and real-time detection of various toxic metal ions.

• 出版日期2016-11-8
• 单位昆明理工大学; 云南大学