A terminal palladium fluoride complex supported by an anionic PNP pincer ligand

作者：Huacuja Rafael; Herbert David E; Fafard Claudia M; Ozerov Oleg V^*

来源：Journal of Fluorine Chemistry, 2010, 131(11): 1257-1261.

DOI：10.1016/j.jfluchem.2010.07.010

• Palladium
• Pincer
• PNP
• Phosphine
• Fluoride

A terminal palladium (II) fluoride complex ((PNP)-P-F)PdF (where (PNP)-P-F is a an anionic fluoro-substituted diarylamido/bis(phosphine) pincer ligand) has been prepared and characterized spectroscopically and structurally An X-ray diffraction study revealed an approximately square-planar environment about Pd and a short Pd-F bond distance ((PNP)-P-F)PdF reacted with silanes containing electron-withdrawing groups on Si by exchange of fluoride with one of the sub

• 出版日期2010-11