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摘要
A series of novel thiourea based receptors (1-12) with different signaling units and spacers have been synthesized for the detection of cyanide ion. Among these receptors, 4,4'-bis-[3-(4-cyanophenyl) thiourea]diphenyl sulfide 6 and 4,4'-bis-[3-(3-cyanophenyl)thiourea] diphenyl sulfide 9 exhibited selective detection of cyanide by the naked-eye as well as by UV-Vis spectroscopy. Furthermore, the chemosensor is insensitive to the presence of other environmentally relevant anions. The chromogenic transformation permits the detection of cyanide (TBA(+) and K(+) salts) in the natural environment.
- 出版日期2011
