A HYSCORE investigation of bimetallic titanium-vanadium microporous catalysts: elucidating the nature of the active sites

作者：Maurelli Sara; Chiesa Mario^*; Giamello Elio; Leithall Rebecca M; Raja Robert

来源：Chemical Communications, 2012, 48(69): 8700-8702.

DOI：10.1039/c2cc33997h

Vanadium and titanium bimetallic AlPO-5 molecular sieves have been synthesized and characterized by means of Electron Spin Echo detected EPR and Hyperfine Sublevel Correlation (HYSCORE) spectroscopy. Direct evidence for framework substitution of redox-active Ti ions and VO2+ units at Al sites is provided through the detection of large P-31 hyperfine couplings.

• 出版日期2012