Novel hybrids of Cu2+ ternary complexes of salicylidene-amino acid Schiff base with phenanthroline (or bipyridine) intercalated in Mg/Al-NO3-layered double hydroxide

作者：Wang, Ming-Zhao^*; Li, Ying; Ji, Jin-Jin; Huang, Gai-Ling; Zhang, Xin; Li, Si-Hui; Yang, Xiao-Jing

来源：Chinese Chemical Letters, 2013, 24(7): 593-596.

DOI：10.1016/j.cclet.2013.03.040

• Layered double hydroxides
• Ternary copper complexes
• Intercalation
• Characterization
• Stability in solution

Four Cu2+ complexes of salicylidene-amino acid Schiff base with 1,10-phenanthroline (Phen) or 2,2'-bipyridine (Bipy) were successfully intercalated in interlayer galleries of Mg/Al-NO3-layered double hydroxide (LDH) by the swelling-restored method. The hybrids were characterized by elemental analysis, X-ray diffraction, FT-IR spectra, UV-vis DRS, TG-DTA and SEM observation. Good protection of the complexes by LDH in neutral and weak acidic solutions was revealed by UV spectra, cyclic voltammograms and luminescence spectra.

• 出版日期2013-7
• 单位北京师范大学