A triphenylene-based conjugated microporous polymer: construction, gas adsorption, and fluorescence detection properties

作者：Han, Jie^*; Fan, Xia; Zhuang, Zhan-Zhong; Song, Wei-Chao; Chang, Ze; Zhang, Ying-Hui; Bu, Xian-He

来源：RSC Advances, 2015, 5(20): 15350-15353.

DOI：10.1039/c4ra13696a

• POROUS ORGANIC POLYMERS
• HIGH-SURFACE-AREA
• AROMATIC FRAMEWORK
• STORAGE
• EXPLOSIVES
• SEPARATION
• HYDROGEN
• STABILITY
• PHASE

A triphenylene-based conjugated microporous polymer (TP-CMP) has been synthesized and shows high surface area (S-BET = 1104 m(2) g(-1)) and remarkable uptakes of H-2 (7.08 mmol g(-1) at 77 K and 900 mmHg) and CO2 (3.37 mmol g(-1) at 273 K and 900 mmHg). In addition, it could be utilized to detect nitrobenzene selectively via fluorescence quenching.

• 出版日期2015
• 单位南开大学