Molecular beam deposition of high-permittivity polydimethylsiloxane for nanometer-thin elastomer films in dielectric actuators

作者：Weiss Florian M; Madsen Frederikke B; Topper Tino; Osmani Bekim; Leung Vanessa; Mueller Bert

来源：Materials and Design, 2016, 105: 106-113.

DOI：10.1016/j.matdes.2016.05.049

• Dielectric elastomer actuator
• Chloropropyl-functional
• Vinyl-terminated siloxane co-oligomer
• Thermal evaporation
• Ultra-violet light curing
• Atomic force microscopy
• Indentation test
• Surface roughness
• Spectroscopic ellipsometer

To realize low-voltage dielectric elastomer actuators (DEAs) for artificial muscles, a high-permittivity elastomer and a related thin-film deposition technique must be selected. For polydimethylsiloxane, fillers or functionalized crosslinkers have been incorporated into the elastomer to improve dielectric properties. To produce elastomer layers nanometers thin, molecular beam deposition was introduced. We pursue the synthesis of a high-permittivity oligomer, namely a chloropropyl-functional, vinyl-terminated siloxane to be thermally evaporated and subsequent UV curing to form an elastomer. The synthesized oligomer exhibits dielectric permittivity enhanced by 33% and a breakdown increase of 26% with respect to the commercially available oligomer DMS-V05. Films 160 nm thin were fabricated after being evaporated under ultra-high vacuum conditions. Spectroscopic ellipsometery served for film growth monitoring. Using atomic force microscopy, the film surface morphology and mechanics were characterized after growth termination and subsequent curing. The Young's modulus of the elastomer corresponded to (1.8 +/- 0.2) MPa and is thus a factor of two lower than that of DMS-V05. Consequently, the properties of the films prepared by the new elastomer can be quantified by the normalized figure of merit, which estimates to 4.6. The presented approach is an essential step toward the realization of low-voltage DEA for medical applications and beyond.

• 出版日期2016-9-5