A Composite Based on {VO3}(n)(n-) Chain Containing Two Different Types of Organic Ligands

作者：Wang Xinfang; Guo Guiling; Xu Yanqing; Hu Changwen^*

来源：Asian Journal of Chemistry, 2013, 25(6): 3033-3035.

DOI：10.14233/ajchem.2013.13505

• Polyoxometalates
• Polyoxovanadates
• Network
• Cluster

The composite compound, [Cu(1.110-phen)(en)H2O][Cu(en)(2)](0.5)[V3O9] (1,10-phen = 1,10-phenanthroline, en = ethylenediamine) (1) has been prepared by solution diffusion method. Compound 1 consists of on 1D {VO3}(n)(n-) chain are further bridged by [Cu(en)(2)](2+) complexes through Cu center dot center dot center dot O weak interaction to form a 2D network.

• 出版日期2013-6
• 单位北京理工大学