Multiple intramolecular hydrogen bonds in 2,4-di-tert-butyl-6-[N-(2,6-diisopropylphenyl)-P,P-diphenylphosphorimido yl]phenol

作者：Lee Jong Dae; Suh Il Hwan; Kang Sang Ook^*

来源：Acta Crystallographica Section C-Crystal Structure Communications, 2011, 67: O151-O153.

DOI：10.1107/S0108270111009267

The title compound, C38H48NOP, isolated from the reaction of (2-diphenylphosphanyl-4,6-di-tert-butyl)phenol with 2,6-diisopropylphenyl azide at 273 K, can act as an N,O-bidentate ligand. Crystal structure analysis shows a deviation from ideal tetrahedral symmetry around the P atom. The molecule exists as a monomer in the solid state, whose conformation is stabilized via multiple intramolecular hydrogen bonds. Geometric parameters from both experimental and theoretical calculations are compared.

• 出版日期2011-5