Dispersibility and Hydrophobicity Analysis of Titanium Dioxide Nanoparticles Grafted with Silane Coupling Agent

作者：Wang Chaoxia; Mao Haiyan; Wang Chunxia; Fu Shaohai

来源：Industrial & Engineering Chemistry Research, 2011, 50(21): 11930-11934.

DOI：10.1021/ie200887x

The high surface energy of TiO(2) nanoparticulate leads to the aggregation of nanoparticles. The grafted modification of nanoparticles is necessary in order to improve its dispersibility in the organic solvent. The effect of grafted modification with silane coupling agent on dispersibility and lipophilicity of TiO(2) nanoparticles was investigated. The factors of the modification were discussed, such as the amount of silane coupling agent, pH value, and reaction time. The average sizes of the TiO(2) nanoparticles were 200-300 nm. The thermogravimetric analysis (TGA) curves indicated that the TiO(2) nanoparticle surface had been grafted with the silane coupling agent. The zeta potential showed that modified TiO(2) could disperse well in the organic solvent. The lipophilic degree and contact angle suggested that the modified TiO(2) had low surface energy and changed from a hydrophilic nature to a lipophilic nature.

• 出版日期2011-11-2
• 单位江南大学