A general, ring closure metathesis based enantiospecific approach to polyfunctional eudesmane, eremophilane and agarofuran sesquiterpenoids

作者：Mehta G^*; Kumaran RS

来源：Tetrahedron Letters, 2003, 44(37): 7055-7059.

DOI：10.1016/S0040-4039(03)01757-X

An enantiospecific and stereo- and functional group diversity oriented approach to eudesmane, eremophilane and agarofuran sesquiterpenoids from (-)-carvone has been devised. RCM has been employed as the key reaction to generate the highly functionalized eudesmane framework. Further elaboration of the eudesmane framework to agarofurans and biogenetic-type rearrangement to eremophilanes is Outlined.

• 出版日期2003-9-8