Dinuclear methoxido-bridged Cu(II) compounds with 7-azaindole as a ligand: Synthesis, characterization and X-ray structures

作者：van Albada Gerard A; van der Horst Maarten G; Mutikainen Ilpo; Turpeinen Urho; Reedijk Jan^*

来源：Journal of Molecular Structure, 2011, 995(1-3): 130-133.

DOI：10.1016/j.molstruc.2011.04.003

• Copper
• Azaindole
• Structure
• Methoxido-bridged
• EPR

Three novel methoxido-bridged dinuclear Cu(II) compounds with the ligand 7-azaindole (abbreviated as Haza), i.e. [Cu(2)(Haza)(4)(CH(3)O)(2)(ClO(4))(2)] (1), [Cu(2)(Haza)(4)(CH(3)O)(2)(CF(3)SO(3))(2)] (2) and [Cu(2)(Haza)(4)(CH(3)O)(2)(NO(3))(2)](3) have been synthesized and fully characterized by spectroscopy, EPR and X-ray structure analysis. The Cu(II) ions show a tetragonally distorted octahedral geometry, with a CuN(2)O(2) chromophore in the basal plane.

• 出版日期2011-5-31