Dihydroxy(4-thiomorpholinomethyl)benzoic Acid: From Molecular Asymmetry to Diode Characteristics

作者：Lennartz M Christina; Baumert Miriam; Karthaeuser Silvia; Albrecht Markus; Wasers Rainer

来源：Langmuir, 2011, 27(16): 10312-10318.

DOI：10.1021/la201206e

One of the challenges in molecular electronics is to design molecules which can be used as functional units in electronic devices. The subject of our investigations is an asymmetrical molecule, dihydroxy(4-thiomorpholinomethyl)benzoic acid (TMBA), whose structural and electronic properties are characterized. The self-assembly behavior of TMBA on Au(111) surfaces resulting in highly ordered monolayers is obtained using scanning tunneling microscopy (STM). Furthermore, investigations on the electronic properties of the combined metal/molecule system reveal an orbital mediated tunneling process and tunneling decay constants for the carboxylic and thiomorpholino group. Thus, a diode-like character of TMBA is shown to be caused by intrinsic electronic properties of different molecular moieties.

• 出版日期2011-8-16