An Efficient Procedure for the Synthesis of Benzoxazole and Benzothiazole Derivatives Using a H2O2/SiO2-FeCl3 System

作者:Mosslemin Mohammad Hossein; Fazlinia Abbas*
来源:Phosphorus, Sulfur, and Silicon and the Related Elements, 2010, 185(10): 2165-2170.
DOI:10.1080/10426501003598630

摘要

A series of benzoxazole and benzothiazoles was readily prepared from the reaction of ortho-aminophenol/ortho-aminothiophenol and aldehydes using solid silica supported ferric chloride (SiO2-FeCl3) as catalyst followed by oxidation with H2O2 under ambient conditions. Some of advantages of this method are a simple and convenient procedure, easy purification, and shorter reaction times. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.

  • 出版日期2010