An Accessible Approach to Preparing Water-Soluble Mn2+-Doped (CdSSe)ZnS (Core)Shell Nanocrystals for Ratiometric Temperature Sensing

作者：Hsia Chih Hao; Wuttig Anna; Yang Haw^*

来源：ACS Nano, 2011, 5(12): 9511-9522.

DOI：10.1021/nn2025622

• nanothermometer
• green chemistry
• quantum dot
• air stable
• temperature-dependent lifetime

A new synthetic scheme allowing structural modifications to temperature-sensitive and water-soluble D-penicillamine-passivated Mn2+-doped (CdSSe)ZnS (core)shell nanocrystals (MnQDs) was reported using air-stable chemicals. The temperature-dependent optical properties of the nanocrystals were tuned by changing their structure and composition the ZnS shell thickness and the Mn2+-dopant concentration. Thick ZnS shells significantly reduce the Interference of nonradiative transitions on ratiometric emission intensities. High-dopant concentration affords consistent temperature sensitivity. In addition to the new base structure for quantum dot ratiometric temperature sensing via flexible, glovebox-free routes, the results also underscore the generalizability of the emission intensity ratio scheme for temperature sensing, originally proposed for rare-earth-doped materials.

• 出版日期2011-12