A new binuclear Mo-V-Dy-III assembly and its magnetism

作者：Ren, Shi; Ma, Shu-Lin; Xu, Gong-Feng; Gu, Bin; Ma, Yue^*; Wang, Qing-Lun; Liao, Dai-Zheng

来源：Inorganic Chemistry Communications, 2011, 14(7): 1124-1127.

DOI：10.1016/j.inoche.2011.04.004

• Cyano bridge
• 4d-4f bimetallic complex
• Hydrogen-bond
• Spin-orbit coupling

The reaction of [Mo(CN)(8)](3-) with Dy3+ in DMF solvent leads to a new binuclear complex, [Mo(CN)(8)Dy (DMF)(4)(H2O)(3)]center dot H2O (1) (DMF=N,N'-dimethylformamide). Magnetic measurements confirm that 1 presents probably a ferromagnetic interaction between the binuclear complexes.

• 出版日期2011-7
• 单位天津商业大学; 南开大学