Size-Selective Detection of Picric Acid by Fluorescent Palladium Macrocycles

作者:Kumar Sushil; Kishan Ram; Kumar Pramod; Pachisia Sanya; Gupta Rajeev*
来源:Inorganic Chemistry, 2018, 57(4): 1693-1697.
DOI:10.1021/acs.inorgchem.7b02813

摘要

This work presents the synthesis and characterization of two palladium-based fluorescent macro cycles offering hydrogen-bonding cavities of contrasting dimensions. Both palladium macrocycles function as chemosensors for the detection of nitroaromatics, whereas the larger macrocycle not only illustrates nanomolar detection of picric acid but also transports its significant amount from an aqueous to an organic phase.

  • 出版日期2018-2-19