Novel Rh(III) pentaryiethylcyclopentadienyl and Ru(II) cyclopentadienyl complexes containing 1,3,5-triazine-2,4,6-trithiol in trinucleating mode

作者：Trivedi Manoj; Pandey Daya Shankar^*; Zou Ru Qiang; Xu Qiang

来源：Inorganic Chemistry Communications, 2008, 11(5): 526-530.

DOI：10.1016/j.inoche.2007.12.039

• rhodium-Cp
• ruthenium-Cp
• trithiocyanuric acid
• X-ray
• emission
• weak interactions

Two homo-trinuclear complexes [{(n(5)-C5Me5)RhCl}(3)(mu(3)-L)] (1) and [{(eta(5)-C5H5)Ru(PPh3)}(3)(eta(3)-L)] (2) (H3L=2,4,6-trimercapto-1,3,5-triazine) are reported. Both the complexes have been fully characterized by elemental analyses, FAB-MS, IR, NMR, electronic and emission spectral techniques. Molecular structure of I has been authenticated by single crystal X-ray diffraction analyses. Complex I revealed the strong intra- and inter-molecular C-H center dot center dot center dot X (X = Cl, pi) and pi-pi stacking interactions, which play important roles to stabilize crystal space packing.

• 出版日期2008-5