1,4-Bis[(2,2 ':6 ',2 ''-terpyridin-4 '-yl)oxy]butane

作者：Akerman Matthew P^*; Grimmer Craig D; Nikolayenko Varvara I; Reddy Desigan

来源：Acta Crystallographica Section E-Structure Reports Online, 2011, 67: O3478-U1714.

DOI：10.1107/S1600536811050343

The title compound, C(34)H(28)N(6)O(2), has an inversion centre located at the mid-point of the central C-C bond of the diether bridging unit. The central pyridine rings of the terpyridyl units and the diether chain are co-planar: the maximum deviation from the 18-atom mean plane defined by the bridging unit and the central pyridyl ring is for the pyridyl N atom which sits 0.055 (1) angstrom above the plane. The dihedral angles between the terminal pyridine rings with this plane are 10.3 (1) and 37.6 (1)degrees, repectively. In the crystal, weak C-H center dot center dot center dot N interactions link the molecules into infinite chains parallel to the a axis.

• 出版日期2011-12