Anomalous structural and dynamical phase transitions of soft colloidal binary mixtures

作者：Kandar A K; Basu J K^*; Narayanan S; Sandy A

来源：Soft Matter, 2012, 8(39): 10055-10060.

DOI：10.1039/c2sm25774b

We report microscopic structural and dynamical measurements on binary mixtures of homopolymers and polymer grafted nanoparticles at high densities in good solvent. We find strong and unexpected anomalies in the structure and dynamics of these binary mixtures, including appearance of spontaneous orientational alignment, as a function of added homopolymers of different molecular weights. Our experiments point to the possibility of exploiting the phase space in density and homopolymer size, of such hybrid systems, to create new materials with novel structural and physical properties.

• 出版日期2012