Nucleophilic imidoesterification of dicarbonyl compounds with cyanatobenzenes through C-C bond formation

作者：Ma Hang; He Yang; Huang Ruo Feng; Zhang Xiao Hui; Pan Jing; Li Jia Qiang; He Chao; Ling Xue Ge; Wang Xuan Lun; Xiong Yan^*

来源：Chinese Chemical Letters, 2014, 25(10): 1327-1330.

DOI：10.1016/j.cclet.2014.06.008

• Imidoesters
• Cyanatobenzenes
• Dicarbonyl compounds
• Imidoesterification
• Nucleophilic addition

Under neat conditions, an efficient method for synthesis of imidoesters has been developed using cyanatobenzenes and dicarbonyl compounds. Nucleophilic addition spontaneously occurred between the two kinds of materials at room temperature with yields of up to 90%. A mechanism directed towards to the imidoester formation has been proposed.

• 出版日期2014-10
• 单位重庆大学; 重庆理工大学