Developing strongly luminescent platinum(IV) complexes: facile synthesis of bis-cyclometalated neutral emitters

作者:Julia Fabio; Bautista Delia; Gonzalez Herrero Pablo*
来源:Chemical Communications, 2016, 52(8): 1657-1660.
DOI:10.1039/c5cc09566b

摘要

A straightforward, one-pot procedure has been developed for the synthesis of bis-cyclometalated chloro(methyl) platinum(IV) complexes with a wide variety of heteroaromatic ligands of the 2-arylpyridine type. The new compounds exhibit phosphorescent emissions in the blue to orange colour range and represent the most efficient Pt(IV) emitters reported to date, with quantum yields up to 0.81 in fluid solutions at room temperature.

  • 出版日期2016