Molecular Self-Assembled Monolayers and Multilayers for Organic and Unconventional Inorganic Thin-Film Transistor Applications

作者：DiBenedetto Sara A; Facchetti Antonio^*; Ratner Mark A; Marks Tobin J

来源：Advanced Materials, 2009, 21(14-15): 1407-1433.

DOI：10.1002/adma.200803267

Principal goals in organic thin-film transistor (OTFT) gate dieletric research include achieving: (i) low gate leakage currents and good chemical/thermal stability, (ii) minimized interface trap state densities to maximize charge transport efficiency, (iii) compatibility with both p and n channel organic semiconductors, (iv) enhanced capacitance to lower OTFT operating voltages, and (v) efficient fabrication via solution-phase processing methods. In this Review we focus on a prominent class of alternative gate dieletric materials: self-assembled monolayers (SAMs) and multilayers (SAMTs) of organic molecules having good insulating properties and large capacitance values, requisite properties for addressing these challenges. We first describe the formation and properties of SAM on various surfaces (metals and oxides), followed by a discussion of fundamental factors governing charge transport through SAMs. The last section focuses on the roles that SAMs and SAMTs play in OTFTs, such as surface treatments, gate dielectrics, and finally as the semiconductor layer in ultra-thin OTFTs.

• 出版日期2009-4-20
• 单位西北大学