Hydrothermal Syntheses and Crystal Structures of Cd(II) and Cu(II) Complexes Constructed with 1,3,5-Benzenetricarboxylic Acid and Dipyrido[3,2-a:2′,3′-c]phenazine Ligands

作者：Li Xiu-Ying; Wang Lu-Yao; Song Ning; Ma Bo-Nan; Zhang Xing-Jing; Che Guang-Bo^*

来源：Chinese Journal of Structural Chemistry, 2015, 34(11): 1709-1716.

• cadmium(II) complex
• copper(II) complex
• 1,3,5-benzenetricaboxylic acid
• dipyrido[3,2-a:2 ',3 '-c]phenazine
• crystal structure

Two novel coordination compounds, [Cd-2(HBTC)(2)(DPPZ)(2)(H2O)(3)]center dot 2H(2)O (1) and [Cu-2(HBTC)(2)(DPPZ)(2)(H2O)](n). (2) based on 1,3,5-benzenetricarboxylic acid (H3BTC) and dipyrido[3,2-a:2',3'-c]phenazine (DPPZ) ligands, have been constructed under hydrothermal conditions. Two complexes are characterized by elemental analysis, IR and single-crystal X-ray diffraction. Structural analyses show that both complexes 1 and 2 present the three-dimensional supramolecular structures. In addition, two complexes exhibit luminescence property.

• 出版日期2015-11
• 单位吉林师范大学; 长春大学