Activation of H-2 by a highly distorted Rh-II complex with a new C-3-symmetric tripodal tetraphosphine ligand

作者：Wassenaar Jeroen; de Bruin Bas; Siegler Maxime A; Spek Anthony L; Reek Joost N H^*; van der Vlugt Jarl Ivar

来源：Chemical Communications, 2010, 46(8): 1232-1234.

DOI：10.1039/b917632b

Facile oxidation of a sterically encumbered Rh-I complex generates a stable Rh-II metalloradical species; the latter is able to activate H-2 under formation of the corresponding Rh-III complex.

• 出版日期2010