Accurate measurement and physical insight: The X-ray extended range technique for fundamental atomic physics, condensed matter research and biological sciences

作者：Chantler C T^*

来源：Radiation Physics and Chemistry, 2010, 79(2): 117-123.

DOI：10.1016/j.radphyschem.2009.07.022

• Integrated techniques
• X-ray extended range technique
• XAFS
• XANES
• XERT
• Synchrotron science
• Atomic physics
• Organometallic chemistry

Research in core physics or atomic and condensed matter science is increasingly relevant for diverse fields and are finding application in chemistry, engineering and biological sciences, linking to experimental research at synchrotrons, reactors and specialised facilities. Over recent synchrotron experiments and publications we have developed methods for measuring the absorption coefficient far from the edge and in the XAFS (X-ray absorption fine structure) region in neutral atoms. simple compounds and organometallics reaching accuracies of below 0.02%. This is 50-500 times more accurate than earlier methods, and 50-250 times more accurate than claimed uncertainties in theoretical computations for these systems. The data and methodology are useful for a wide range of applications, including major synchrotron and laboratory techniques relating to fine structure, near-edge analysis and standard crystallography. Experiments are sensitive to theoretical and computational issues, including correlation between convergence of electronic and atomic orbitals and wavefunctions. Hence. particularly in relation to the popular techniques of XAFS and XANES (X-ray absorption near-edge structure), this development calls for strong theoretical involvement but has great applications in solid state structural determination. catalysis and enzyme environments, active centres of biomolecules and organometallics. phase changes and fluorescence investigations and others. We discuss key features of the X-ray extended range technique (XERT) and illustrate applications.

• 出版日期2010-2