Aryne Reaction with gamma-Arylallenylcarboxyamides: Unexpected Diels-Alder Cycloaddition

作者：Fu, Haixing; Yang, Yupo; Wei, Zhibin; Zhang, Zhengjuan; Wu, Chunrui^*; Shi, Feng

来源：Asian Journal of Organic Chemistry, 2015, 4(7): 612-615.

DOI：10.1002/ajoc.201500098

• arynes
• Diels-Alder cycloaddition
• gamma-arylallenylcarboxyamides
• phenanthrenes
• structure-reactivity relationship

When gamma-arylallenylcarboxyamides react with arynes, their arylallene moiety reacts in a Diels-Alder fashion, leaving the amide functionality intact.

• 出版日期2015-7
• 单位青岛科技大学; 河南大学