Asymmetric Total Synthesis of Caribenol A

作者:Liu, Lian-Zhu; Han, Jin-Chun; Yue, Guo-Zong; Li, Chuang-Chuang*; Yang, Zhen
来源:Journal of the American Chemical Society, 2010, 132(39): 13608-13609.
DOI:10.1021/ja106585n

摘要

A unified strategy toward the asymmetric total synthesis of carbenol A is reported, featuring intramolecular Diels-Alder (IMDA) and biomimetic oxidation reactions as key steps.