A new visible light bimolecular photoinitiator system for free radical polymerization

作者：Chen, Yu; Li, Guanglei; Han, Junru; Wang, Tao^*

来源：Journal of Photochemistry and Photobiology A: Chemistry , 2011, 222(2-3): 330-335.

DOI：10.1016/j.jphotochem.2011.07.005

• Photopolymerization
• Photochemistry
• Ferrocenium salt
• N-methyl-2-pyrrolidone
• Photoinitiator

A new bimolecular photoinitiator system consisting of a ferrocenium salt (Fc) and N-methyl-2-pyrrolidone (NMP) is developed for free radical photopolymerization under visible light irradiation, which was delivered by a halogen lamp. Photopolymerization profiles of tripropylene glycol diacrylate (TPGDA) show that high conversion can be easily achieved. The processes associated with the Fc/NMP system are investigated by photochemical and electrochemical experiments. The results show that the photoinitiation mechanism of this bimolecular system could occur through charge transfers between Fc and NMP.

• 出版日期2011-8-15
• 单位北京化工大学