A triple thermoresponsive schizophrenic diblock copolymer

作者:Zhang Qilu; Hong Jong Dal; Hoogenboom Richard*
来源:Polymer Chemistry, 2013, 4(16): 4322-4325.
DOI:10.1039/c3py00659j

摘要

This article describes a new class of triple thermoresponsive %26apos;schizophrenic%26apos; diblock copolymer that undergoes transitions from conventional micelles (or vesicles) via unimers to reverse micelles (or vesicles) and finally to a precipitated state upon heating. The various transition temperatures of this copolymer could be well controlled by the concentration of trivalent anion and pH that control the upper critical solution temperature of the poly(dimethylaminoethyl methacrtylate) (PDMAEMA) block or the type of poly(methoxy oligo-ethylenegylol methacrylate) (PmOEGA) to vary the lower critical solution temperature.

  • 出版日期2013