Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine

作者：Horak Kyle T; Velian Alexandra; Day Michael W; Agapie Theodor^*

来源：Chemical communications, 2014, 50(34): 4427-4429.

DOI：10.1039/c4cc00838c

Cofacial Fe-2, Co-2, and Ni-2 complexes supported by a para-terphenyl diphosphine ligand were prepared. Central arene deplanarization and a mu(2):(eta(3),eta(3)) coordination mode suggest partial bisallyl character in the Fe2 and Co2 complexes. An oxidation induced shift in Fe-2-arene binding highlights the non-innocent nature of the arene ligand.

• 出版日期2014