A facile two-phase approach to nearly monodisperse ZnS nanocrystals

作者：Ye Xinyu; Zhuang Weidong^*; Fang Ying; Hu Yunsheng; Zhao Ke; Huang Xiaowei

来源：Materials Chemistry and Physics, 2008, 112(3): 730-733.

DOI：10.1016/j.matchemphys.2008.07.094

• ZnS
• Nanocrystals
• Two-phase approach
• Mechanism

In this work, we report a facile two-phase approach to synthesize nearly monodisperse cubic zinc sulfide nanocrystals. Toluene and water were used as separate solvents for zinc stearate and sodium sulfide, respectively, and oleic acid was used as a stabilizing ligand for the nanocrystals. Their photophysical properties were investigated by UV-vis absorption spectra. Transmission electron microscopy and selected area electron diffraction in combination with X-ray powder diffraction indicated the presence of pure cubic ZnS nanocrystals in good crystallization with the size ranged from about 2.0 to 5.0 nm in diameters. The possible mechanism was also presented.

• 出版日期2008-12-20
• 单位北京有色金属研究总院; 江西理工大学; 商丘师范学院