A pure inorganic 1D chain based on {Mo8O28} clusters and Mn(II) ions: [Mn(H2O)(2)Mo8O28](n)(6n-)

作者：Zhang, Xiaofen; Yan, Yonghong; Wu, Lizhou; Yu, Chengxin; Dong, Xinbo; Hu, Huaiming; Xue, Ganglin^*

来源：Solid State Sciences, 2016, 51: 18-23.

DOI：10.1016/j.solidstatesciences.2015.11.005

• Polyoxometalates
• Octamolybdate
• Inorganic 1D chain
• Catalytic activities

A new pure inorganic polymer, (NH4)(6n)[Mn(H2O)(2)Mo8O28)](n)(H2O)(2n) (1), has been synthesized and characterized by elemental analyses, IR spectrum, UVevis absorption spectra, TG-DSC and electrochemical studies. In 1, [Mo8O28](8-) anions act as tetradentate ligands and are alternately linked by Mn(H2O)(2)(2+) ions into a one- dimensional chain structure. It is interesting that 1 represents the first example of pure inorganiceinorganic hybrid based on octamolybdate and transition metal ions. Moreover, it was indicated that 1 had definite catalytic activities on the probe reaction of benzyl alcohol oxidation to benzaldehyde with H2O2.

• 出版日期2016-1
• 单位西北大学