摘要

The solid compound formulated as [Cu(4,7-phen)(H2O)(3)](ClO4)(2) . (4,7-phen)(2) (phen = phenanthroline) has been shown by single-crystal structural analysis to be a three-dimensional network with hexagonal channels, constructed of one-dimensional S-shaped [Cu(4,7-phen)(H2O)(3)](n)(2n ) cationic chains and solvated 4,7-phen molecules, linked through extensive hydrogen bonds and pi-pi interactions.