摘要
In situ generated palladium on aluminum oxide provides an active catalytic system for Matsuda-Heck reactions in gram-scale. The novel catalyst proceeded through a significantly higher catalytic activity compared to the classical Pd/C system. Based on the high catalytic activity the first alpha,beta,beta-triarylation of methyl acrylate in good yields could be provided in one-step.
- 出版日期2016-12-16