A planar chiral [2.2]paracyclophane derived N-heterocyclic stannylene

作者：Piel Isabel; Dickschat Julia V; Pape Tania; Hahn F Ekkehardt^*; Glorius Frank

来源：Dalton Transactions, 2012, 41(45): 13788-13790.

DOI：10.1039/c2dt31497e

The reaction of pseudo-ortho-4,12-N,N%26apos;-diphenyldiamino-[2.2]paracyclophane ((+/-)-3) with Sn[N(SiMe3)(2)](2) results in the formation of the monomeric planar chiral N-heterocyclic stannylene (+/-)-4, featuring a unique [2.2]paracyclophane backbone, which has been characterized by an X-ray diffraction study.

• 出版日期2012