Activity of continuous flow synthesized Pd-based nanocatalysts in the flow hydroconversion of furfural

作者：Garcia Olmo Antonio J; Yepez Alfonso; Balu Alina M; Prinsen Pepijn; Garcia Araceli; Maziere Audrey; Len Christophe; Luque Rafael^*

来源：Tetrahedron, 2017, 73(38): 5599-5604.

DOI：10.1016/j.tet.2017.02.056

• Furfural conversion
• Flow chemistry
• Pd
• Nanoparticles
• Hydrogenation
• Heterogeneous catalysis

A number of synthesized supported Pd nanomaterials on aluminosilicate supports were investigated in the continuous flow hydroconversion of furfural to a range of furanic derivatives as compared to a commercial Pd/C catalyst. Excellent furfural conversions (>60%) and varying selectivities to products at mild temperatures (90 degrees C) could be obtained for most catalytic systems, with interesting selectivities to furfuryl alcohol (FOL), 2-methylfuran (MF) and tetrahydrofurfuryl alcohol (THFOL) depending on type of Pd catalyst. A significant deactivation with time on stream was observed for continuous flow synthesized nanomaterials with respect to commercial 5%Pd/C.

• 出版日期2017-9-21