A New Porous Three-Dimensional Iron(II) Coordination Polymer with Solvent-Induced Reversible Spin-Crossover Behavior

作者：Meng, Yan^*; Dong, Yan-Jie; Yan, Zheng; Chen, Yan-Cong; Song, Xiao-Wei; Li, Quan-Wen; Zhang, Chuan-Lei; Ni, Zhao-Ping^*; Tong, Ming-Liang^*

来源：Crystal Growth & Design, 2018, 18(9): 5214-5219.

DOI：10.1021/acs.cgd.8b00657

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A new Hofmann-type porous coordination polymer [Fe(dpni){Ag-(CN)(2)}(2)]center dot 4CH(3)CN (dpni = N,N'-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide) with the topology of pcu net has been synthesized. It exhibits two-step spin-crossover behavior. Moreover, reversible changes between incomplete and two-step spin-crossover properties were associated with the desorption/resorption of the CH3CN solvent molecules.

• 出版日期2018-9
• 单位安庆师范大学; 嘉兴学院; 中山大学