A pendant phosphorus Lewis acid: route to a palladium-benzoyl derived phosphorane

作者:Firth Kelly F; Mobus Juri; Stephan Douglas W*
来源:Chemical Communications, 2016, 52(97): 13967-13970.
DOI:10.1039/c6cc08561j

摘要

The traditional use of phosphorus compounds is as ligands for transition metals, however herein we synthesize Lewis acidic fluoro-phosphonium cation appended to a palladium complex and effect CO insertion into a Pd-C bond to obtain an unprecedented metal-benzoyl derived phosphorane.

  • 出版日期2016