Phosphido Pincer Complexes of Palladium as New Efficient Catalysts for Allylation of Aldehydes

作者：Mazzeo Mina^*; Lamberti Marina; Massa Antonio; Scettri Arrigo; Pellecchia Claudio; Peters Jonas C

来源：Organometallics, 2008, 27(22): 5741-5743.

DOI：10.1021/om8008537

Palladium complexes supported by tridentate phosphido diphosphine ligands (P(o-C(6)H(4)PR(2))(2): 1, R = (i)Pr; 2, R = Ph) have been synthesized, characterized, and tested as catalysts for the electrophilic allylation of aldehydes. The palladium complex 2 resulted in an interesting catalyst for electrophilic allylation in the presence of allyltributyltin, giving good yields under very mild reaction conditions and even in the absence of the solvent.

• 出版日期2008-11-24