A Sn-IV-Porphyrin-Based Metal-Organic Framework for the Selective Photo-Oxygenation of Phenol and Sulfides

作者：Xie, Ming-Hua; Yang, Xiu-Li; Zou, Chao; Wu, Chuan-De^*

来源：Inorganic Chemistry, 2011, 50(12): 5318-5320.

DOI：10.1021/ic200295h

• HETEROGENEOUS ASYMMETRIC CATALYSIS
• COORDINATION POLYMERS
• HYDROGEN STORAGE
• EPOXIDATION
• OXIDATION
• WATER
• ALDEHYDES
• NETWORK
• IONS

A functional tin(IV)-porphyrin derivative was used as a building block to construct a novel 3D porous metal-organic framework (MOF). The MOF is built up from tin(IV)-porphjrin struts linking up Zn atoms and formates joining Sn-IV centers. The immobilization of the photoactive Sn-porphyrins in the channel walls lets the MOF present remarkable photocatalytic activities for the oxygenation of phenol and sulfides, resulting in excellent yields and remarkable selectivity in heterogeneous phases.

• 出版日期2011-6-20
• 单位浙江大学