科研之友
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摘要
In-situ studies of Al-Si eutectic growth has been carried out for the first time by X-ray video microscopy during directional solidification of Al-Si-Cu alloys with and without Sr-addtions The unmodified eutectics showed distinctive non isothermal growth dynamics where Si-crystals attained needle-like tip morphologies and progressed under significantly higher undercooling than Al leading to formation of an irregular eutectic with Si as the leading phase and subsequent nucleation of Al on the Si-surfaces In the Sr-modified alloys the eutectic reaction was found to be strongly suppressed occurring with low nucleation frequencies at undercoolings in the range 10-18 K In the Cu-enriched melt the eutectic front was found to attain meso-scale interface perturbations sometimes evolving into equiaxed cellular rosettes in order to accommodate to the long-range redistribution of Cu from the composite eutectic interface The eutectic front also attained short-range microscale interface perturbations consistent with characteristics of a fibrous Si growth However further improvements in spatial resolution are required in order to study the microscale structure formation in greater detail Evidence was found in support of Si nucleation occurring on potent particles suspended in the melt Yet both with Sr-modified and unmodified alloys Si precipitation alone was not sufficient to facilitate the eutectic reaction which apparently required additional undercooling for Al to form on the Si-particles To what extent nucleation mechanisms in the Cu-enriched systems are transferable to binary or commercial Al Si alloys remains uncertain
- 出版日期2010
