A supramolecular chloride-water tape of six- and five-membered rings as template in the crystal structure of di-mu(2)-hydroxo-bis(diethylenetriamine) dicopper(II) dichloride trihydrate, {[Cu(dien)(mu-OH)]Cl-+(-)}(2) center dot 3H(2)O

作者：Braban Mircea; Haiduc Ionel^*; Noltemeyer Mathias; Roesky Herbert W; Schmidt H G

来源：Inorganic Chemistry Communications, 2008, 11(4): 442-445.

DOI：10.1016/j.inoche.2007.09.030

• crystal structure
• supramolecular self-assembly
• water-chloride assembly
• hydrogen bonds
• copper(II) complexes
• hydroxo-bridged dimer

Water molecules in association with chloride anions form supramolecular self-assembled tapes made of fused five- and six-membered rings, [(H2O)(3)Cl(OH)] and [(H2O)(4)Cl(OH)], serving as a template in the crystal structure of dinuclear {[Cu(dien)(mu-OH)]Cl-+(-))(2) center dot 3H(2)O, based upon a Cu-2(mu-OH)(2) central moiety.

• 出版日期2008-4