A [24-MC-6] Zinc Metallacoronate with a Nonsteroidal Antiinflammatory Drug as the Constructing Ligand

作者：Tarushi Alketa; Kastanias Filippos; Psycharis Vassilis; Raptopoulou Catherine P; Psomas George; Kessissoglou Dimitris P^*

来源：Inorganic Chemistry, 2012, 51(14): 7460-7462.

DOI：10.1021/ic3010757

The interaction of ZnCl2 with 2-dipyridyl-ketonoxime (=Hpko) and flufenamic acid (=Hfluf) in a basic methanolic solution leads to the formation of a hexanuclear 2,4-membered metallacoronate, [Zn-6(OH)(2)(pko)(4)(fluf)(6)] (1), with a [Zn-O-C-O] repeat unit and a nonsteroidal antiinflammatory drug as the constructing ligand. Compound 1 retains its structure in a dimethyl sulfoxide solution, as shown by H-1 NMR spectroscopy and molar conductance.

• 出版日期2012-7-16