Alkoxycarbonylation of Industrially Relevant Anilines Using Zn4O(O2CCH3)(6) as Catalyst

作者：Reixach Elisenda; Haak Robert M; Wershofen Stefan; Vidal Ferran Anton^*

来源：Industrial & Engineering Chemistry Research, 2012, 51(50): 16165-16170.

DOI：10.1021/ie301315k

An efficient procedure is presented for the alkoxycarbonylation of industrially important amines using environmentally friendly alkyl carbonates as reagents and Zn4O(OAc)(6) as catalyst. Aromatic amines in particular (thirteen examples) consistently give high yields (up to 98%), regardless of the electronic properties of the substituents or the ring substitution pattern.

• 出版日期2012-12-19