A novel Sm-Co polymeric complex formed via metal-mediated oxidation-hydrolysis of orotic acid in a hydrothermal reaction

作者：Li, X; Cao, R^*; Sun, DF; Shi, Q; Bi, WH; Hong, MC

来源：Inorganic Chemistry Communications, 2003, 6(7): 815-818.

DOI：10.1016/S1387-7003(03)00114-X

• hydrothermal synthesis
• oxidation
• hydrolysis
• metal-mediated

A novel Sm-Co coordination polymer constructed by orotic acid (2,6-dioxo-1,2,3,6-tetrahydropyrimidine-4-carboxylic acid, H(3)dtpc) and oxalate (ox(2-)), {[Sm2Co(ox)(2)(Hdtpc)(2)(H2O)(6)].2H(2)O}(n) (1), was prepared by metal-mediated oxidation-hydrolysis of orotic acid in a hydrothermal reaction. Crystallographic data for 1: triclinic, space group P - 1 with a = 8.2266(4), b = 9.2895(4), c = 9.7934(5) Angstrom, alpha = 75.347(1), beta = 69.708(1), gamma = 72.665(2)degrees, V = 660.66(5) Angstrom(3), Z = 2, Dc = 2.4832 g/cm(3). Magnetic susceptibility measurement for 1 is consistent with the existence of weak anti-ferromagnetic interaction.

• 出版日期2003-7
• 单位中国科学院福建物质结构研究所; 结构化学国家重点实验室