Derivatization and in situ metallation of phthalocyanines using click chemistry

作者：Yilmaz Yusuf; Sener M Kasim^*; Erden Ibrahim; Avciata Ulvi

来源：Polyhedron, 2009, 28(16): 3419-3424.

DOI：10.1016/j.poly.2009.07.033

• Click chemistry
• Phthalocyanine
• Supramolecular association
• Metallation

Dialkyl (3,4-dicyanophenyl)propargylmalonates were prepared by the reaction of propargyl bromide and the potassium salt of dialkyl-3,4-dicyanophenylmalonates. A cyclotetramerization reaction was achieved in pentanol in the presence of DBU without protective/deprotective chemistry, affording the peripherally tetrasubstituted alkynyl phthalocyanines. Subsequently, in situ metallation and 'clicking' were employed for the first time as an efficient and quantitative route to tetratriazole-functionalized phthalocyanines.

• 出版日期2009-11-3